Developing Chemistry

Fixer

Dissolves the unexposed halide so the image stops changing and can be seen in light.

3Stop & Fix 35mm1204 × 5
Wear PPE & Ventilate Nitrile gloves Eye protection Cross-flow air Label every bottle Dispose of fixer properly
Stop & Fix stage
Fixer — line drawing with key specifications
Key specifications
TypesRapid (ammonium thiosulfate) · Standard (sodium thiosulfate)
Film dilution1:4 from concentrate, or as the data sheet states
Paper dilution1:9 for fibre papers in a two-bath regime
Film fixing time3–5 min (rapid), 10–15 min (standard)
Paper fixing time2–3 min per bath in a two-bath regime
Capacity≈ 24 films or 40 8 × 10 prints per litre
Indicator testClear a film leader in 30 s — if slower, replace
Archival noteUse two baths and never exceed capacity

Overview

After development the film or paper is still full of silver halide that was never exposed. Fixer dissolves it — converting the insoluble halide into soluble complexes that the wash can carry away. Until that happens the image is still light-sensitive and still developing.

Rapid fixers based on ammonium thiosulfate work in three to five minutes; the older sodium thiosulfate "hypo" takes ten to fifteen. The trade-off is capacity and odour: rapid fixers are more expensive, work faster, and smell far less.

The critical discipline is knowing when fixer is spent. Silver accumulates in the solution and fixation slows. A two-bath fix — half the time in bath one, half in bath two — is the standard archival practice, because the second bath stays nearly fresh and finishes the job properly.

What it does well

  • Makes the image permanent and viewable in daylight
  • Rapid fixers cut film fixing to three to five minutes
  • Two-bath fixing is the archival standard for fibre prints
  • Clears film leaders — a simple way to test strength
  • Reusable until capacity is reached

Safety notes

Read before you use itFixers are acidic and contain sulfites; some people react to them. Ventilate, wear gloves, and never mix fixer with an acid stop in the same container — the reaction releases sulfur dioxide. Do not pour spent fixer down the drain if your local regulations say otherwise; many areas require it to go to hazardous waste.

Working notes

  • Test strength by dropping in a scrap of unprocessed film leader: it should clear in 30 seconds.
  • Fix at the same temperature as the developer to avoid reticulation.
  • For archival work, use two baths and keep bath two for the finish.
  • Never use the same container for fixer and developer — trace contamination fogs prints.

Compatible with

35mm1204 × 5RC and fibre papers

Related

Pairs well with

More in Developing Chemistry
Developing Chemistry Stop & Fix

Stop Bath

A dilute acid that halts development in seconds and protects the fixer.

Stop & Fix stage
Developing Chemistry Stop & Fix

Hypo Clear

A washing aid that swaps the fixer out of the emulsion so the wash can finish the job.

Stop & Fix stage
Finishing & Archiving Finish

Print Washer

A tank that keeps fresh water moving past every print until the fixer is gone.

Printing & Finishing stage
Developing Chemistry Develop

Film Developer

The reducing agent that turns exposed silver halide into visible metallic silver.

Developing stage